The ties are to be played in the week commencing September 21.
Arsenal v West Brom
Chelsea v QPR
Bolton v West Ham
Barnsley v Burnley
Hull v Everton
Leeds v Liverpool
Manchester United v Wolves
Manchester City v Fulham
Sunderland v Birmingham
Peterborough v Newcastle
Carlisle v Portsmouth
Nottingham Forest v Blackburn
Stoke v Blackpool
Scunthorpe v Port Vale
Preston v Tottenham
Aston Villa v Cardiff